Raji is the youngest daughter of late Chathamkulangara Kunjunni Ezhuthachan and Narayani Amma. She is married to V. Gopalan, son of late Pulikkal Velu Ezhuthachan and Parukutty Amma, Kannambra, Palakkad District. They are currently residing in Cochin.

They are blessed with a daughter Dhanya, who is married to Praveen, son of Dr. K. Sethumadhavan and Smt. Prabhalakshmi, Thrayambaka Kizhakkiveettil, Kanniyampuram, Ottappalam. Praveen & Dhanya currently run a website designing company in Cochin. They are blessed with three sons Pranav, Swaroop & Dhruv.